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Synthesis of 11-and 12-membered rings by a direct cyclization method

 

作者: Denis Brillon,   Pierre Deslongchamps,  

 

期刊: Canadian Journal of Chemistry  （NRC Available online 1987）
卷期: Volume 65, issue 1  

页码: 43-55

 

ISSN:0008-4042

 

年代: 1987

 

DOI:10.1139/v87-010

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

The malonate anion intramolecular displacement of propargylic or allylic chlorides, and of primary bromide, in eleven- and twelve-carbon chains containing either two, one, or no unsaturation centers leads to the corresponding 11- and 12-membered ring compounds in good yield under conditions of medium dilution.

 

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