首页   按字顺浏览 期刊浏览 卷期浏览 Usefulness of Hysteresis Curves for Studying Temperature Effects on Ises Responses
Usefulness of Hysteresis Curves for Studying Temperature Effects on Ises Responses

 

作者: M. Teresa,   S.D. Vesconcelos,   AdélioA. S. C. Machado,  

 

期刊: Analytical Letters  (Taylor Available online 1988)
卷期: Volume 21, issue 11  

页码: 1987-2002

 

ISSN:0003-2719

 

年代: 1988

 

DOI:10.1080/00032718808059885

 

出版商: Taylor & Francis Group

 

关键词: Hysteresis curves;isothermal slope coefficient;isotherm1 potential coefficient;isohermal impotentis1 point;conductive epoxy-based ion-selective electrodes;all-solid-state electrodes;silver(1) sulphide electrode;iodide electrode

 

数据来源: Taylor

 

摘要:

A procedure for study of the effects of the temperature on the response of ion-selective electrodes in which isothermal hysteresis cum determined at several concentrations are used for obtaining the temperature variation parameters (isothermal slope and potential coefficients and isopotential points) is proposed. The procedure was tested against the classic procedure in which calibration curves are obtained at different temperatures. 'All -solid-state' Ag2S and Ag2S/Agl electrodes with sensors applied to silver- and copper-loaded epoxy supports (and commercial electrodes, for comparison) were used for this purpose. The values of the temperature parameters obtained by the two procedures (in the raw 10–60°C) are compared. This comparison show that the present procedure yields acceptable values of temperature parameters for cases like the studied where the hysteresis is not very produced.

 

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