Rate Study of the Alkline Hydrolysis of Nicotinamide Using an Ammonia Gas-Sensing Electrode
作者:
C.E. Efstathiou,
D.P. Nikolelis,
T.P. Hadjiioannou,
期刊:
Analytical Letters
(Taylor Available online 1982)
卷期:
Volume 15,
issue 14
页码: 1179-1191
ISSN:0003-2719
年代: 1982
DOI:10.1080/00032718208064432
出版商: Taylor & Francis Group
关键词: Nicotinamide alkaline hydrolysis;Rate constants;Ammonia gas-sensing electrode
数据来源: Taylor
摘要:
The hydrolysis of nicotinamide in alkaline solutions was studied. An ammonia gas-sensing electrode was used to follow the formation of ammonia. A technique making use of simulated reactions has been developed to calibrate the electrode under dynamic conditions overcoming problems arising because of the relatively slow response of the sensor. A general expression has been derived for the pseudo first-order rate constant valid over the concentration range 0.005 to 0.10 M nicotinamide, 0.1 to 0.5 M hydroxide and the temperature range 22° to 31° C, under constant ionic strength (0.5 M NaOH + NaC1O4).
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