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Conductivity Properties of Some Tetraalkylammonium Iodides in the Water+N,N-Dimethylformamide Mixtures at 298.15 K

 

作者: Adam Szejgis,   Adam Bald,   Jerzy Gregorowicz,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1997)
卷期: Volume 35, issue 3  

页码: 165-173

 

ISSN:0031-9104

 

年代: 1997

 

DOI:10.1080/00319109708030584

 

出版商: Taylor & Francis Group

 

关键词: Conductances;solution of tetraalkylammonium salts;mixtures of water with N,N-dimethylformamide;walden products

 

数据来源: Taylor

 

摘要:

Conductance measurements are reported for iodides of tetramethylammonium (Me4NI), teraethylammonium (Et4NI), tetrapropylammonium (Pr4NI), tetrabutylammonium (Bu4NI), and tetrahexylammonium (Hex4NI), in the water+N,N-dimethylformamide (DMF) mixtures over the whole composition range, except for Me4NI and Hex4NI, where the composition range are 0-50 mol% and 50-100 mol% of DMF, respectively, at 298.15 K. The data obtained have been analyzed by the Fuoss-Justice equation, in terms of the limiting molar conductances (Δ0), the Walden products (Δ0η) and the association constant (KA). Variation in the Walden products with solvent composition are briefly discussed. The results obtained here were also compared with the literature data.

 

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