Conductivity Properties of Some Tetraalkylammonium Iodides in the Water+N,N-Dimethylformamide Mixtures at 298.15 K
作者:
Adam Szejgis,
Adam Bald,
Jerzy Gregorowicz,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1997)
卷期:
Volume 35,
issue 3
页码: 165-173
ISSN:0031-9104
年代: 1997
DOI:10.1080/00319109708030584
出版商: Taylor & Francis Group
关键词: Conductances;solution of tetraalkylammonium salts;mixtures of water with N,N-dimethylformamide;walden products
数据来源: Taylor
摘要:
Conductance measurements are reported for iodides of tetramethylammonium (Me4NI), teraethylammonium (Et4NI), tetrapropylammonium (Pr4NI), tetrabutylammonium (Bu4NI), and tetrahexylammonium (Hex4NI), in the water+N,N-dimethylformamide (DMF) mixtures over the whole composition range, except for Me4NI and Hex4NI, where the composition range are 0-50 mol% and 50-100 mol% of DMF, respectively, at 298.15 K. The data obtained have been analyzed by the Fuoss-Justice equation, in terms of the limiting molar conductances (Δ0), the Walden products (Δ0η) and the association constant (KA). Variation in the Walden products with solvent composition are briefly discussed. The results obtained here were also compared with the literature data.
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