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Ag Ion Transport and Deposition in &agr; Quartz

 

作者: H. B. Vanfleet,   G. S. Baker,   P. Gibbs,  

 

期刊: Journal of Applied Physics  (AIP Available online 1963)
卷期: Volume 34, issue 4  

页码: 891-897

 

ISSN:0021-8979

 

年代: 1963

 

DOI:10.1063/1.1729556

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Contact of a negatively charged microprobe to the (0001) face of a silver‐backed Madagascar &agr;quartz crystal at temperatures between 300–573°C produced four distinct types of visible decorations. The most prominent of these were conducting metallic platelets on the basal plane about 0.4 &mgr; thick, with surface areas ranging up to the dimensions of the anode. The growth of these platelets appeared to take place only at the periphery, and to be thermally activated with dependence upon field &egr; of the form exp[−(H0−&bgr;&egr;½)/RT], where &bgr;=0.32 kcal/[mole(V/cm)½] andH0=38 kcal/mole. Metallic platelets which formed deep within the crystal bulk, having relatively large surface area usually caused the crystal to fracture. The migration of silver through the crystal bulk was observed to take place only in the [0001] direction. Geometric patterns showing the sixfold symmetry of the basal plane were observed to form, at or near the crystal surface, within a fraction of a second upon the application of a negative probe to the (0001) face. Probe currents, both axial and equatorial, were found to be thermally activated with energies between 38 and 39 kcal/mole for conduction not involving the transport of silver ions. Platelet formation in synthetic quartz crystals differed markedly from that for natural quartz. Instead of a conducting metallic platelet, an irregular dendritic growth appeared.

 

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