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Tetrafluoro-p-Benzoquinone Radicals: Chemical Exchange as Evidenced by Cidep

 

作者: M.T. Craw,   M.C. Depew,   J.K. S. Wan,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1988）
卷期: Volume 21, issue 6  

页码: 437-446

 

ISSN:0038-7010

 

年代: 1988

 

DOI:10.1080/00387018808062724

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The CIDEP characteristics of radicals derived from tetra-fluoro-p-benzoquinone have been studied. An alternating linewidth effect in the time-resolved CIDEP spectra was observed when a hydroxylic/non hydroxylic solvent mixture was used. The results are discussed in terms of chemical exchange between the neutral and anionic quinone radicals.

 

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