The Acidity of Clay Minerals in Polymerizations and Related Reactions
作者:
D.H. Solomon,
JeanD. Swift,
A.J. Murphy,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1971)
卷期:
Volume 5,
issue 3
页码: 587-601
ISSN:0022-233X
年代: 1971
DOI:10.1080/00222337108061046
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The chemical activity of mineral fillers, under conditions similar to those encountered in filled-polymer systems, has been studied. It is shown that, contrary to previous views, the alumino-silicates have strongly acidic surfaces and that this surface acidity influences the chemical reactions in polymeric composites. Although the number of acid sites is significantly less than those of cracking catalysts, the strength of the sites is of a similar order of magnitude. A study of the infrared spectra of pyridine adsorbed on kaolin has shown that both Lewis and Brønsted acid sites are present. The ratio of Lewis to Brønsted acid sites varies with the free moisture content of the clay.
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