GRAIN GROWTH AND DENSIFICATION IN PALLADIUM OXIDE PARTICLES DURING SPRAY PYROLYSIS
作者:
A. S. GURAV,
T. C. PLUYM,
T. T. KODAS,
S. E. PRATSINIS,
期刊:
Chemical Engineering Communications
(Taylor Available online 1996)
卷期:
Volume 151,
issue 1
页码: 211-226
ISSN:0098-6445
年代: 1996
DOI:10.1080/00986449608936549
出版商: Taylor & Francis Group
关键词: Grain growth;Densification;Palladium oxide;Spray pyrolysis
数据来源: Taylor
摘要:
A model for aerosol-phase densification of particles during their synthesis by spray pyrolysis is presented. The model was used to describe the evolution of the specific surface area of PdO powders synthesized at temperatures between 400 to 800 °C (residence times 27.9 to 22.7 s). Surface areas and grain sizes ranged between 56 m2/g and 4 nm at 400 °C to 3.2 m2/g and 40 nm at 800 °C The characteristic coalescence lime was determined as: τ= 1.7 x 1013T d3exp(1.3 x 105/RT) [for lattice diffusion] and t = 2.7 x 1019Td4exp (1.6 x 105/RT) [for grain boundary diffusion] (τ is in seconds,Tin degrees Kelvin, R is 8.314J/(mol.K)and d is in meters), but the data and model did not allow identification of the specific mechanism. The model provides a general approach for correlating changes in particle surface area with reactor operating conditions that is applicable to a wide variety of materials.
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