Cyclo- and Cyclized Diene Polymers. XXII. Kinetics of Cyclopolymerization of Isoprene with C2H5AlCl2+ TiCl4Catalyst
作者:
B. Matyska,
H. Antropiova,
M. Svestka,
N.G. Gaylord,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1970)
卷期:
Volume 4,
issue 7
页码: 1529-1547
ISSN:0022-233X
年代: 1970
DOI:10.1080/00222337008069368
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The polymerization of isoprene in aromatic solvents, catalyzed by an ethylaluminum dichloride-titanium tetrachloride system, proceeds via a complex of the monomer with the catalyst, chain growth occurring when a monomer cation-radical is formed through the transfer of one electron from the monomer to the catalyst. The deactivation of the active species results from the dissociation of the complex polymer cation-radical to free ions. The over-all reaction is a nonstationary process during which the concentration of free ions increases and the concentration of the active species decreases. A reaction mechanism is proposed which leads to kinetic expressions that quantitatively describe the experimental data.
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