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Kinetics of the First Order Autocatalytic Decomposition Reaction of Nitrocellulose (13.86% N)

 

作者: Peng‐Jiang Guo,   Rong‐Zu Hu,   Bin‐Ke Ning,   Zheng‐Quan Yang,   Ji‐Rong Song,   Qi‐Zhen Shi,   Gui‐E Lu,   Jin‐You Jiang,  

 

期刊: Chinese Journal of Chemistry  (WILEY Available online 2004)
卷期: Volume 22, issue 1  

页码: 19-23

 

ISSN:1001-604X

 

年代: 2004

 

DOI:10.1002/cjoc.20040220106

 

出版商: Wiley‐VCH Verlag GmbH&Co. KGaA

 

关键词: first order autocatalytic reaction;NC;Kinetics;DSC

 

数据来源: WILEY

 

摘要:

AbstractThe kinetics of the first order autocatalytic decomposition reaction of nitrocellulose (NC, 13.86% N) was studied by using DSC. The results show that the DSC curve for the initial 508 of conversion degree of NC can be described by the first order autocatalytic equationand that for the latter 50% conversion degree of NC described by the reaction equations.

 

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