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A short Overview on the Binary and some New Ternary Sodium GICs

 

作者: Albert Hérold,   Jean-François Marěché,   Michèle Lelaurain,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 1998)
卷期: Volume 310, issue 1  

页码: 43-49

 

ISSN:1058-725X

 

年代: 1998

 

DOI:10.1080/10587259808045312

 

出版商: Taylor & Francis Group

 

关键词: graphite;sodium;halogens;intercalation;thermodynamics

 

数据来源: Taylor

 

摘要:

In a first part a thermodynamic explanation of the differences between the binary sodium GICs and those of the other alkali metals (low stages lack, octal structures at the high stages) is proposed. The second part mainly concerns the cointercalation of sodium and its halides leading to ternary GICs. Their composition and structure are connected to the reaction temperature and to the structure and lattice energy of the free halides.

 

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