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13C‐NMR. Analysis of Dihydrogranaticin Methyl Ester. A case of mixed biogenesis

 

作者: Alberto Arnone,   Lorenzo Camarda,   Rosanna Cardillo,   Giovanni Fronza,   Lucio Merlini,   Rosanna Mondelli,   Gianluca Nasini,   Jan St. Pyrek,  

 

期刊: Helvetica Chimica Acta  （WILEY Available online 1979）
卷期: Volume 62, issue 1  

页码: 30-33

 

ISSN:0018-019X

 

年代: 1979

 

DOI:10.1002/hlca.19790620105

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

AbstractThe13C‐NMR. spectrum of dihydrogranaticin methyl ester has been completely analyzed. Feeding experiments of CH313COONa to a culture ofStreptomyces olivaceushave shown that only a sixteen carbon moiety of the antibiotic granaticin is of polyketide origin, thus confirming the hypothesis of a mixed biogenesis for this natural substanc

 

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