THE EXTRACTION OF AMERIC1UM (III) BY MIXTURES OF TRIBUTYLPHOSPHATE WITH DIBUTYL-N,N-DIETHYLCARBAMOYL- PHOSPHONATE AND -METHYLPHOSPHONATE (DBDECP AND DBDECMP)
作者:
AnthonyC. Muscatello,
JamesD. Navratil,
MiltonE. Killion,
期刊:
Solvent Extraction and Ion Exchange
(Taylor Available online 1983)
卷期:
Volume 1,
issue 1
页码: 127-139
ISSN:0736-6299
年代: 1983
DOI:10.1080/07366298308918396
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The chemistry of the mixed solvent extractants, dibutyl-N, N-diethylcarbamoylmethylphosphonate (DBDECMP)-tri -£-butyl phosphate (TBP), using carbon tetrachloride diluent, was studied for extracting americium (III) from nitric acid at various concentrations and temperatures. Synergistic extraction of americium was observed and an extraction mechanism is proposed based on slope analysis, infrared studies, and temperature variation studies. Similar studies were performed with dibutyl-N, N-diethylcarbamoylphosphonate (DBDECP)
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