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INTERACTION BETWEEN THE CARBONYL GROUP AND A SULFUR ATOM. PART XI PHOTOELECTRON SPECTRA OF SOME 2-ALKYLTHIOCYCLOPENTANONES

 

作者: Camille Sandorfy,   JerryW. Lewis,   Blanka Wladislaw,   IsabelC. C. Calegäo,  

 

期刊: Phosphorus and Sulfur and the Related Elements  （Taylor Available online 1983）
卷期: Volume 16, issue 3  

页码: 287-291

 

ISSN:0308-664X

 

年代: 1983

 

DOI:10.1080/03086648308080481

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The helium I photoelectron spectra of some 2-alkylthio-cyclopentanones are reported. The IP′s related to the sulfur and carbonyl lone pairs are compared to those in the corresponding cyclopentanones and cyclopentyl alkyl sulfide. The observed stabilization of both orbitals cannot be explained by the mutual inductive effects of the sulfur and carbonyl group. The conformational dependence of this effect is discussed.

 

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