Polymere charge‐transfer‐komplexe auf der basis von polyvinylalkoholacetalen, 4
作者:
Ulrich GeißLer,
Rolf C. Schulz,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1982)
卷期:
Volume 183,
issue 7
页码: 1669-1683
ISSN:0025-116X
年代: 1982
DOI:10.1002/macp.1982.021830709
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractPartially acetalisized poly(vinyl alcohol)s with degrees of acetalization between 39 and 60% were prepared by reaction of poly(vinyl alcohol) with 9‐isobutyl‐3‐carbazolealdehyde(5a)or 3‐formyl‐9‐((S)‐2‐methylbutyl)carbazole(5b). Complex formation constants and ε‐values of the charge‐transfer complexes with ethylenetetracarbonitrile, 2,5‐cyclohexadien‐1, 4‐diylidenedimalonodinitrile, 2,4,5,7‐tetranitro‐9‐fluorenone, and 2,4,7‐trinitro‐9‐fluorenone were determined. Circular dicroism measurements of the optically active CT‐comple
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