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High frequency rotational mode in liquid methyl chloride

 

作者: A. Gerschel,   T. Grochulski,   Z. Kisiel,   L. Pszczolkowski,   K. Leibler,  

 

期刊: Molecular Physics  （Taylor Available online 1985）
卷期: Volume 54, issue 1  

页码: 97-117

 

ISSN:0026-8976

 

年代: 1985

 

DOI:10.1080/00268978500100081

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Complex permittivity measurements in liquid methyl chloride have been completed over the whole frequency range at temperatures and densities scanning the orthobaric curve, from 176 K up to 363 K. A report on the experimental set-ups and the accuracies obtained is given. Relaxation parameters are derived in the frame of Debye theory, and Hill's distribution of damped resonances is used to construct a model for librational absorption.

 

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