Recent Developments on the Clathrates M8Si46and MxSi136(M ˭ Na, K, Rb, Cs, Ba; 0 ≤ x ≤ 24) as Inclusion Compounds of Alkali Metals in Connected Fullerene-like Cages of Silicon
作者:
Christian Cros,
Edouard Reny,
Michel Pouchard,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 310,
issue 1
页码: 199-204
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808045336
出版商: Taylor & Francis Group
关键词: clathrates;Fullerenes;inclusion compounds
数据来源: Taylor
摘要:
In the structure of the clathrate-type silicides M8Si46and MxSi136(M ˭ Na, K, Rb, Cs, Ba; 0 ≤ x ≤ 24), the silicon atoms form 3D covalent sublattices which correspond to the association of two kinds of fullerene-like cages : Si20and Si24, and Si20and Si28respectively. The M atoms are trapped at the centre of all or part of the two different cages and are distributed according to a A15 and a C15 type sublattice, respectively. Due to their clathrate-type structure, these silicides exhibit original and interesting physical properties. The two structures are described and a short review is given on the previous and recent developments on these cage-like compounds.
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