Structural and Oxygen Storage/Release Properties of CeO2-Based Solid Solutions
作者:
Alessandro Trovarelli,
期刊:
Comments on Inorganic Chemistry
(Taylor Available online 1999)
卷期:
Volume 20,
issue 4-6
页码: 263-284
ISSN:0260-3594
年代: 1999
DOI:10.1080/02603599908021446
出版商: Taylor & Francis Group
关键词: ceria;CeO2;solid solutions;rare-earth oxides;auto-exhaust catalysis;oxygen storage capacity
数据来源: Taylor
摘要:
The use of mixed-oxides containing CeO2as oxygen storage/release components is discussed with special focus on the applications of these materials in auto-exhaust catalytic converters. Ceria easily forms solid solutions with transition-metal/rare-earth oxides over a wide composition range. The incorporation of dopants like Zr4+, Pr3/4+, Tb3/4+into the cubic fluorite lattice of CeO2strongly affects the structural and energetic properties of the materials by lowering activation energy for oxygen migration and by increasing reducibility of the cerium cation. This augments both total and kinetic oxygen exchange between the solid and the gas phase under conditions typically encountered in real systems.
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