Single-trap-controlled transient hopping process in molecularly doped polymers
作者:
H.-J. Yuh,
D. Abramsohn,
M. Stolka,
期刊:
Philosophical Magazine Letters
(Taylor Available online 1987)
卷期:
Volume 55,
issue 6
页码: 277-282
ISSN:0950-0839
年代: 1987
DOI:10.1080/09500838708214697
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Time-of-flight measurements on molecularly doped polymers have revealed that, the transient current shapes change from being virtually non-dispersive to highly dispersive (featureless) and back to non-dispersive as the shallow trap concentration is increased from 0 to ∼ 1 mol%. The shallow traps were introduced into the molecularly doped system by mixing the charge-transporting molecule with small amounts of another transporting molecule having a significantly lower ionization potential. The results support the model of Schmidlin for single-trap-controlled transport. Based on this model, the attempt-to-escape frequency and the activation energy for escape from the trap are found to be ∼4 × 1012s−1and 0·56eV, respectively.
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