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Studies of Radical Alternating Copolymerization. II. Influence of Charge Transfer Complex between Comonomers on the Microstructure of the Copolymers. Case of Maleic Anhydride and Vinyl Acetate

 

作者: Claude Caze,   Claude Loucheux,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1981)
卷期: Volume 15, issue 1  

页码: 95-105

 

ISSN:0022-233X

 

年代: 1981

 

DOI:10.1080/00222338108066433

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Vinyl acetate and maleic anhydride are known to give 1:1 radical alternating copolymerization regardless of the monomer feed composition. The mechanism of this copolymerization involves free monomers and a complex between them (charge transfer complex). We undertook a study of the microstructure of different alternating copolymers (bylH,13C NMR, and thermogravimetric analysis). Starting from the results obtained, we determined the influence of the participation of the complex on the microstructure of the alternating copolymers.

 

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