Studies of Radical Alternating Copolymerization. II. Influence of Charge Transfer Complex between Comonomers on the Microstructure of the Copolymers. Case of Maleic Anhydride and Vinyl Acetate
作者:
Claude Caze,
Claude Loucheux,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1981)
卷期:
Volume 15,
issue 1
页码: 95-105
ISSN:0022-233X
年代: 1981
DOI:10.1080/00222338108066433
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Vinyl acetate and maleic anhydride are known to give 1:1 radical alternating copolymerization regardless of the monomer feed composition. The mechanism of this copolymerization involves free monomers and a complex between them (charge transfer complex). We undertook a study of the microstructure of different alternating copolymers (bylH,13C NMR, and thermogravimetric analysis). Starting from the results obtained, we determined the influence of the participation of the complex on the microstructure of the alternating copolymers.
点击下载:
PDF (396KB)
返 回