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A Trapped Ion Analyzer Cell for Ion Cyclotron Resonance Spectroscopy

 

作者: Robert T. McIver,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1970)
卷期: Volume 41, issue 4  

页码: 555-558

 

ISSN:0034-6748

 

年代: 1970

 

DOI:10.1063/1.1684576

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Ion cyclotron resonance spectroscopy has been adopted for the detection of gaseous ions formed within an analyzer cell of new design. Ions formed by electron impact have been trapped within the analyzer cell for as long as 0.10 sec and detected with a half‐height mass resolution of 5000. Even at pressures of 10−5Torr ion‐molecule reactions of high kinetic order may be observed. An important feature of the trapped ion analyzer cell is that it retains the capability of the ICR double resonance experiment for elucidating the reaction sequence occurring in a complex mixture of primary ions and high order product ions. A pulsed magnetic field detection scheme accurately limits the residence time of the ions within the trapped ion analyzer cell.

 

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