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Adsorption of water on rhenium studied by XPS

 

作者: P. D. Schulze,   S. L. Shaffer,   R. L. Hance,   D. L. Utley,  

 

期刊: Journal of Vacuum Science&Technology A: Vacuum, Surfaces, and Films  （AIP Available online 1983）
卷期: Volume 1, issue 1  

页码: 97-99

 

ISSN:0734-2101

 

年代: 1983

 

DOI:10.1116/1.572321

 

出版商: American Vacuum Society

 

关键词: adsorption;heavy water;rhenium;dissociation;sorptive properties;photoelectron spectroscopy;high temperature;oxygen;x radiation;photoelectron spectroscopy

 

数据来源: AIP

 

摘要:

The adsorption of D2O on clean polycrystalline rhenium has been studied by x‐ray photoelectron spectroscopy. At 305 K, only dissociative adsorption occurs; at 135 K, D2O adsorbs molecularly with the formation of multilayer ice at high converges. The molecular D2O desorbs at 180 K with the formation of an OD complex.

 

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