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Relationship of the Acid-Induced13C Chemical-Shift Change in the α-Carbon Atom to the Stretching Frequency of the Hydroxy Group in Saturated Alcohols

 

作者: M. Takasuka,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1982）
卷期: Volume 15, issue 3  

页码: 233-242

 

ISSN:0038-7010

 

年代: 1982

 

DOI:10.1080/00387018208062665

 

出版商: Taylor & Francis Group

 

关键词: Hydroxy Stretching Frequency;Acid-induced13C Chemical-shift change;CNDO/2 Calculation

 

数据来源: Taylor

 

摘要:

A good linear relationship was found between the acid-induced13C chemical shift change of the α-carbon atom and the OH stretching frequency of the hydroxy group in some saturated alcohols. The relationship is discussed with model calculations using the CNDO/2 method.

 

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