The Simultaneous Spectrophotometric Determination of Osmium and Ruthenium
作者:
EugeneW. Berg,
H.E. Moseley,
期刊:
Analytical Letters
(Taylor Available online 1969)
卷期:
Volume 2,
issue 5
页码: 259-267
ISSN:0003-2719
年代: 1969
DOI:10.1080/00032716908051298
出版商: Taylor & Francis Group
关键词: osmium;ruthenium;spectrophotometry;bromo complexes;thiourea
数据来源: Taylor
摘要:
A spectrophotometric procedure is described for the simultaneous determination of osmium and ruthenium in the form of bromo complexes. It was found that a blue ruthenium-thiourea complex could be formed in 6.7MHBr solutions while the osmium could be maintained as the hexabromoosmate complex. Absorption maxima were at 620 μ for the ruthenium complex and at 446 μ for the osmium complex. Molar absorptivities for the ruthenium complex were 2.47 × 103at 620 μ and 763 at 446 μ. For the osmium complex molar absorptivities were 328 at 620 μ and 6.81 × 103at 446 μ. The method is useable over the range of 5 to 30 ppm with an absolute error of = 1 ppm over the range. Other platinum metals interfere.
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