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FT-IR (6600-50 cm−1) and FT-Raman (3500—70 cm−1) Studies of the Tetranuclear Bismuth (III) Complex (C5H5NH)6Bi4Cl18.

 

作者: G. Bator,   Th. Zeegers-Huyskens,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1997）
卷期: Volume 30, issue 2  

页码: 321-329

 

ISSN:0038-7010

 

年代: 1997

 

DOI:10.1080/00387019708006991

 

出版商: Taylor & Francis Group

 

关键词: Bismuth (III) complex;pyridinium ion;FT-IR and FT-Raman spectra

 

数据来源: Taylor

 

摘要:

The FT-IR and FT-Raman spectra of the tetranuclear Bi(III) complex Bi(C5H5NH)6Bi4Cl18are investigated. The spectroscopic data reflect the non-equivalence of the pyridinium ions and suggest a strong distortion of the octahedral structure for the Bi4Cl18group. The near-infrared data show that like in the fundamental region, protonation of pyridine results in a frequency increase of several combination bands.

 

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