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Molecular electric properties and nuclear and vibrational relaxation

 

作者: Josep Martí,   José Luis Andrés,   Juan Bertrán,   Miquel Duran,  

 

期刊: Molecular Physics  （Taylor Available online 1993）
卷期: Volume 80, issue 3  

页码: 625-633

 

ISSN:0026-8976

 

年代: 1993

 

DOI:10.1080/00268979300102501

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The effects of nuclear relaxation and change in vibrational molecular energy are accounted for in the theoretical determination of the molecular properties of HF, CH4, and C2H4. A method based on a finite-difference technique is employed. An analysis of the influence of these contributions versus the purely electronic contribution is made, together with an appraisal of the effect of vibrational excitation.

 

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