Compositionally modulated sputtered InSb/GaSb superlattices: Crystal growth and interlayer diffusion
作者:
A. H. Eltoukhy,
J. E. Greene,
期刊:
Journal of Applied Physics
(AIP Available online 1979)
卷期:
Volume 50,
issue 1
页码: 505-517
ISSN:0021-8979
年代: 1979
DOI:10.1063/1.325643
出版商: AIP
数据来源: AIP
摘要:
Compositionally modulated single‐crystal InSb/GaSb superlattice structures have been grown by multitarget sputtering in order to investigate the effects of film growth parameters on the defect structure, abruptness, and coherence of sputtered heterojunctions. The layer thicknesses studied ranged from 12 to 70 A˚. The polycrystalline–to–single‐crystal ’’transition temperature’’Tcwas found to decrease with decreasing average film‐substrate lattice mismatch and modulation period, &Lgr;. The &Lgr;‐dependence resulted from a decrease in the coherence between layers and the associated increased amount of plastically accommodated strain which occurred with increasing layer thickness. Increasing the film growth temperatureTSand decreasing the period of the composition modulation also resulted in a decrease in the density of microtwins and low‐angle dislocation boundaries which were observed in all films. Single and multiple {111} twins were identified. For a given set of growth conditions on cleaved BaF2and NaCl substrates, a significant decrease inTcand structural defect densities could be achieved by coating the substrates with thin (<300A˚) single‐crystal InSb layers which were deposited and annealedinsituimmediately prior to superlattice film growth. Variations inTSbetween 150 and 320 °C had no effect on either the amplitude of composition modulation in deposited films or on the minimum layer thickness &Lgr;minobtainable from a given set of sputtering conditions. &Lgr;minwas, however, found to be dependent on the sputtering pressure and was limited by ion‐bombardment‐enhanced diffusion during film growth. A model is discussed for determining bombardment‐enhanced diffusion coefficientsD* as a function of growth conditions using measured x‐ray superlattice diffraction intensities. Values ofD* obtained in this way were several orders of magnitude larger than thermal diffusion coefficients found from postannealing experiments.
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