“Reagentless” Flow Analysis Determination of Hydrogen Peroxide by Electrocatalyzed Luminol Chemiluminescence
作者:
JamesE. Atwater,
JamesR. Akse,
Jeffery DeHart,
RichardR. Wheeler,
期刊:
Analytical Letters
(Taylor Available online 1997)
卷期:
Volume 30,
issue 1
页码: 21-31
ISSN:0003-2719
年代: 1997
DOI:10.1080/00032719708002287
出版商: Taylor & Francis Group
关键词: reagentless;chemiluminescence;electrocatalyzed;luminol;peroxide.
数据来源: Taylor
摘要:
Flow analysis methodology is presented for the determination of micromolar levels of aqueous hydrogen peroxide by luminol chemiluminescence. Adjustment of the pH to alkaline conditions and addition of the luminophore are implemented using in-line flow-through beds containing crystalline media. The requirement for a homogeneous catalyst is eliminated by electrochemical initiation of luminescence. Traditional laboratory reagents are replaced by packed beds containing solid phase basification media, and crystalline luminol. The methodology is suitable for application in both continuous flow and flow injection analysis configurations.
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