Polymer Effect on Catalysis by Macromolecules/Transition Metal Complexes
作者:
Francesco Ciardelli,
Carlo Carlini,
Paolo Pertici,
Giorgio Valentini,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1989)
卷期:
Volume 26,
issue 2-3
页码: 327-347
ISSN:0022-233X
年代: 1989
DOI:10.1080/00222338908051977
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The present status of research in the field of macromolecules/transition metal complexes is critically reviewed on the basis of selected examples both from the authors′ laboratories and other laboratories around the world. The substantial lack of inertness of the polymeric ligand (the polymer effect) is examined and shown to occur in most cases during preparation of the macromolecule/transition metal complex as well as during its catalytic use. This behavior is attributed and confirmed as due to the polydentate ligand character of the macromolecules and to the effect of physical and chemical parameters which can be varied over large ranges. Future work is duscussed for the development of the field in suitable directions.
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