Degradation processes at the cathode/organic interface in organic light emitting devices with Mg:Ag cathodes
作者:
Hany Aziz,
Zoran Popovic,
Carl P. Tripp,
Nan-Xing Hu,
Ah-Mee Hor,
Gu Xu,
期刊:
Applied Physics Letters
(AIP Available online 1998)
卷期:
Volume 72,
issue 21
页码: 2642-2644
ISSN:0003-6951
年代: 1998
DOI:10.1063/1.121442
出版商: AIP
数据来源: AIP
摘要:
We report electroluminescence degradation studies on tris(8-hydroxyquinoline) aluminum(Alq3)-based organic light emitting devices (OLEDs) with Mg:Ag cathodes in ambient conditions. The nonemissive spots in the OLEDs are studied via optical and fluorescence microscopy and via microscopic infrared spectroscopy. Studies reveal that a majority of the nonemissive spots are caused by the growth ofMg(OH)2sites at theAlq3/Mg:Aginterface, associated with local degradation of theAlq3layer. In addition, the growth of elevated cathode bubbles, which also lead to nonemissive spots, is found to be caused by gas evolution from the galvanic corrosion of the Mg/Ag couple as well as from the electrolysis of absorbed moisture. ©1998 American Institute of Physics.
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