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A new statement of the second law of thermodynamics

 

作者: Alan Macdonald,  

 

期刊: American Journal of Physics  (AIP Available online 1995)
卷期: Volume 63, issue 12  

页码: 1122-1127

 

ISSN:0002-9505

 

年代: 1995

 

DOI:10.1119/1.18018

 

出版商: American Association of Physics Teachers

 

关键词: ADIABATIC PROCESSES;ENTROPY;HEAT TRANSFER;IRREVERSIBLE PROCESSES;TEMPERATURE DEPENDENCE;THERMODYNAMICS

 

数据来源: AIP

 

摘要:

A new statement of the second law of thermodynamics is given. The law leads almost effortlessly, for very general closed systems, to a definition of absolute entropyS, a demonstration that ΔS≥0 in adiabatic processes, a definition of temperature, and a demonstration thatdS≥δQ/Tin quasistatic processes. Entropy is given a clear physical meaning.

 

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