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Resolution of Additive Mixtures into Source Components and Contributions: A Compositional Approach

 

作者: Karen Bandeen-Roche,  

 

期刊: Journal of the American Statistical Association  (Taylor Available online 1994)
卷期: Volume 89, issue 428  

页码: 1450-1458

 

ISSN:0162-1459

 

年代: 1994

 

DOI:10.1080/01621459.1994.10476883

 

出版商: Taylor & Francis Group

 

关键词: Air pollution;Identifiability;Latent variables;Measurement error;Mixture model;Source apportionment

 

数据来源: Taylor

 

摘要:

Methodology is developed for analysis of observations that are random linear combinations of point “source components.” Dual goals are to estimate unknown source identities and to characterize the mixing process by which sources contribute to the observations. Observations are modeled as arising from a mixture distribution, whereby the mixing component characterizes the process of interest and the kernel component captures measurement error. A parametric model is proposed, and maximum likelihood estimates of source and mixing parameters are obtained. Estimate performance is investigated by Monte Carlo simulation. Major results are devoted to studying a constraint framework within which model identifiability is guaranteed. For maximal generality, a compositional framework is applied throughout. The resolution problem discussed in this article is common in the physical sciences. For illustration, an application to air pollution data is presented.

 

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