Silver(I) Complexes of 3‐Substituted 1‐Methyl‐perhydro‐1,2,4‐triazine‐5,6‐dithionesHeterocyclic triazine compounds such as 1‐methyl‐perhydro‐1,2,4‐triazin‐5,6‐dithiones react with silver salts forming complex species [AgL2]+(L = triazinedithione). In water the complexes are unstable owing to ligand hydrolysis. Stable solid complex [AgL2]Br(L = 1,3,3‐trimethyl‐perhydro‐1,2,4‐triazine‐5,6‐dithione) can be obtained by the digestion of AgBr‐microcrystals with the triazinedithione in methanol. As shown by X‐ray crystal structure analysis the silver ion in this complex is coordinated trig