首页   按字顺浏览 期刊浏览 卷期浏览 Direct observation of the main-chain conformation of a combined liquid-crystal polymer
Direct observation of the main-chain conformation of a combined liquid-crystal polymer

 

作者: L. Noirez,   H. Poths,   R. Zentel,   C. Strazielle,  

 

期刊: Liquid Crystals  (Taylor Available online 1995)
卷期: Volume 18, issue 1  

页码: 123-127

 

ISSN:0267-8292

 

年代: 1995

 

DOI:10.1080/02678299508036601

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The conformation of the main-chain (backbone) of a combined main-chain/side-chain liquid crystalline polymer has been qualitatively determined by small angle neutron scattering in the oriented nematic, the smectic A and the smectic C phases. The polymer backbone presents only a weak anisotropy, of prolate shape, in the nematic and the smectic C phases. A stronger reorientation of the backbones in the direction of the applied magnetic field is measured for the SAphase. However, this anisotropy remains small compared to the stretching of a main-chain liquid crystal polymer and the smectic structure results apparently from side-chain ordering. On the other hand, hydrodynamic measurements show that the combined polymer, in solvent, is as flexible as a polystyrene chain. This result is compatible with an explanation for the weak observed anisotropy.

 

点击下载:  PDF (413KB)



返 回