A bivariate distribution functionH(x, y) with marginalsF(x) andG(y) is said to be generated by an Archimedean copula if it can be expressed in the formH(x, y) = ϕ–1[ϕ{F(x)} + ϕ{G(y)}] for some convex, decreasing function ϕ defined on [0, 1] in such a way that ϕ(1) = 0. Many well-known systems of bivariate distributions belong to this class, including those of Gumbel, Ali-Mikhail-Haq-Thélot, Clayton, Frank, and Hougaard. Frailty models also fall under that general prescription. This article examines the problem of selecting an Archimedean copula providing a suitable representation of the dependence structure between two variatesXandYin the light of a random sample (X1,Y1), …, (Xn,Yn). The key to the estimation procedure is a one-dimensional empirical distribution function that can be constructed whether the uniform representation ofXandYis Archimedean or not, and independently of their marginals. This semiparametric estimator, based on a decomposition of Kendall's tau statistic, is seen to be √n-consistent, and an explicit formula for its asymptotic variance is provided. This leads to a strategy for selecting the parametric family of Archimedean copulas that provides the best possible fit to a given set of data. To illustrate these procedures, a uranium exploration data set is reanalyzed. Although the presentation is restricted to problems involving a random sample from a bivariate distribution, extensions to situations involving multivariate or censored data could be envisaged.