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Yield Stress Master Curves for Various Polymers below Their Glass Transition Temperatures

 

作者: Jerome J. Lohr,  

 

期刊: Transactions of the Society of Rheology  (AIP Available online 1965)
卷期: Volume 9, issue 1  

页码: 65-81

 

ISSN:0148-6055

 

年代: 1965

 

DOI:10.1122/1.549008

 

出版商: The Society of Rheology

 

数据来源: AIP

 

摘要:

Yield stress master curves are presented for poly(methyl methacrylate), polystyrene, polyvinyl chloride, and polyethylene terephthalate. Tensile yield stress was measured at strain rates varying from 0.003 in./in./min to 300 in./in./min and at temperatures varying from approximately 15°C above the glass transition temperatureT0to at least 100°C belowT0.The resultant yield, or in the brittle temperature range, failure stress, when plotted as a function of logarithm of strain rate, has been shifted laterally to construct a yield stress master curve similar in concept to the well‐known stress relaxation master curve. These master curves cover from 12 to 18 decades of shifted strain rate. The master curve for each material has a characteristic slope which leads, in each case, to a simple equation relating yield stress to strain rate and temperature and is applicable for temperatures fromT0to approximately 100°C belowT0.The temperature‐dependent shift factorsaTof each material were determined for both yield stress and stress relaxation over the temperature range. Comparison of theseaTcurves shows that in both the ductile and brittle temperature ranges of each material, the shape of the yield stress and stress relaxationaTcurves are very similar. However, the absolute magnitude of the change with temperature can be substantially different. Two possible explanations for this difference are offered.

 

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