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Adsorption of Nonionic Surfactant from Its Aqueous Solution onto Commercial Rubber

 

作者: M.N. SHALABY,   A.A. EL-FEKY,  

 

期刊: Journal of Dispersion Science and Technology  (Taylor Available online 1999)
卷期: Volume 20, issue 5  

页码: 1389-1406

 

ISSN:0193-2691

 

年代: 1999

 

DOI:10.1080/01932699908943859

 

出版商: Taylor & Francis Group

 

关键词: nonionic surfactant;adsorption onto hydrophobic surface;polymer;and rubber.

 

数据来源: Taylor

 

摘要:

Adsorption of Ethoxylated Nonyl Phenol (ENP) surfactant from its aqueous solution onto a commercial tire cutting from different sites. Outer Peristalitic (O.P.), Outer Smouth (O.S.), and Internal Tire (I.T.) is studied after different immersion times, 24, 48, 72, and 144 hrs at 30° C. The adsorption isotherms are determined by a surface tension method. A two stepped L-type isotherm is characteristic below the CMC of ENP; above this concentration the isotherm deviates from the L-type and the slope of the isotherm increases sharply. A Langmuir fit has been found below the CMC of ENP. From the maximum amounts adsorbed at pseudo-plateau (Tmaxof the tested samples it was found that the efficiency of adsorption onto the rubber surface decreases in the order, O.P. > O.S. > I.T.

 

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