The monoclinic phase in PZT: New light on morphotropic phase boundaries
作者:
B. Noheda,
J. A. Gonzalo,
R. Guo,
S.-E. Park,
L. E. Cross,
D. E. Cox,
G. Shirane,
期刊:
AIP Conference Proceedings
(AIP Available online 1900)
卷期:
Volume 535,
issue 1
页码: 304-313
ISSN:0094-243X
年代: 1900
DOI:10.1063/1.1324468
出版商: AIP
数据来源: AIP
摘要:
A summary of the work recently carried out on the morphotropic phase boundary (MPB) of PZT is presented. By means of x-ray powder diffraction on ceramic samples of excellent quality, the MPB has been successfully characterized by changing temperature in a series of closely spaced compositions. As a result, an unexpected monoclinic phase has been found to exist in between the well-known tetragonal and rhombohedral PZT phases. A detailed structural analysis, together with the investigation of the field effect in this region of compositions, have led to an important advance in understanding the mechanisms responsible for the physical properties of PZT as well as other piezoelectric materials with similar morphotropic phase boundaries. ©2000 American Institute of Physics.
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