Molecular Structures of Ethylene, Allene and Ethylene Oxide and Bridged π-Bond
作者:
Keinosuke Hamada,
期刊:
Spectroscopy Letters
(Taylor Available online 1989)
卷期:
Volume 22,
issue 8
页码: 1093-1100
ISSN:0038-7010
年代: 1989
DOI:10.1080/00387018908053960
出版商: Taylor & Francis Group
关键词: Molecular Structure;CH2=CH2;CH2CH2;Bridged;π-Bond
数据来源: Taylor
摘要:
Valence considerations suggest the plane symmetrical form (point group D2h) for an ethylene molecule. The observed spectra show that there are no bands that occur in the Raman as well as the infrared spectrum of an ethylene gas, proving that the molecule has D2hsymmetry where the molecule has a center of symmetry. From valence theory one would expect for an allene molecule that the C = C = C chain is linear but that the two CH2groups lie in planes at right angles to each other and passing through the C = C = C axis, that is, that the molecule belongs to point groups D2d. The obtained Raman and infrared data of an allene can be interpreted according to D2dsymmetry.
点击下载:
PDF (264KB)
返 回