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Maleic anhydride-co-stearyl methacrylate copolymers. Synthesis, characterization, and some aspects of the solution behavior

 

作者: Angel Leiva,   Ligia Gargallo,   Deodato Radić,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1998)
卷期: Volume 37, issue 1  

页码: 45-57

 

ISSN:0022-2348

 

年代: 1998

 

DOI:10.1080/00222349808220454

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Maleic anhydride-stearyl methacrylate copolymer was synthesized by radical polymerization. The copolymer was fractionated and characterized by dynamic and static light scattering (DLS and SLS) experiments in different concentration regimes. Seven fractions of low polydispersity index (<1.18) were studied. A typical behavior corresponding to good and theta () solvents, according to the classical theories for polymers in solution, was found in the dilute regime. The results indicate in a semiquantitative way that this copolymer shows a normal behavior in the dilute regime. The rigidity parameters σ and C∞ show flexibility of the polymer chain, due to the incorporation of the maleic anhydride (MA) units, when the copolymer is compared with those corresponding to other poly(methacrylates) previously reported. In the semidilute regime and depending on the solvent nature, aggregation of the copolymer was detected. The aggregation was analyzed in terms of the values of the autocorrelation function determined by dynamic light scattering.

 

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