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Charge Ordering and Lattice Modulation in Quasi-One-Dimensional Halogen-Bridged Binuclear Metal Complexes

 

作者: Makoto Kuwabara,   Kenji Yonemitsu,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 2000)
卷期: Volume 343, issue 1  

页码: 47-52

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008023501

 

出版商: Taylor & Francis Group

 

关键词: MMX chain;dimerization;Peierls-Hubbard model

 

数据来源: Taylor

 

摘要:

Ground state phase diagrams of the MMX chains are studied in a one-dimensional dimerized 3/4-filled model by exactly diagonalizing 12-site clusters. Experimentally observed phases are reproduced by changing relative strengths of an electron-lattice coupling, the inter-dimer transfer integral, and an elastic constant whose variation is roughly estimated from the interatomic spacing, the species of the halogen ions and the presence/absence of counter ions.

 

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