Long‐range shielding by cyclopropyl groups in 10‐spirocyclopropyl‐9,10‐dihydroanthracenes
作者:
Mary T. Ryder,
Stuart M. Rosenfeld,
期刊:
Organic Magnetic Resonance
(WILEY Available online 1983)
卷期:
Volume 21,
issue 1
页码: 24-27
ISSN:0030-4921
年代: 1983
DOI:10.1002/omr.1270210107
出版商: John Wiley&Sons Limited
数据来源: WILEY
摘要:
AbstractTheperiprotons in a series of 10‐spiroclopropyl‐9,10‐dihydroanthracenes have been shown to have shifts consistent with large (0.43‐0.55 ppm) long‐range shielding effects exerted by neighboring cyclopropyl groups. The shieldings are expected to be sensitive to variations in preferred conformation and, since the range of observed shifts for the five compounds studied is relatively small, it is concluded that all exhibit similar conformational p
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