Flow Birefringence and Stress. V. Correlation of Recoverable Shear Strains with Other Rheological Properties of Polymer Solutions
作者:
Wladimir Philippoff,
Frederick H. Gaskins,
John G. Brodnyan,
期刊:
Journal of Applied Physics
(AIP Available online 1957)
卷期:
Volume 28,
issue 10
页码: 1118-1123
ISSN:0021-8979
年代: 1957
DOI:10.1063/1.1722590
出版商: AIP
数据来源: AIP
摘要:
The correlation of normal stress with the shear stress and flow birefringence of flowing solutions has been extended to include the recoverable shear strainswhich can be measured directly by a rotational viscometer in ``recoil.'' This has been shown experimentally with solutions of a high‐viscosity nitro‐cellulose inn‐butyl acetate and a viscous polyisobutylene. These results show that the principal axes of the tensors of stress, strain, and optical anistropy coincide, even when no constant shear modulus (shear compliance) exists.
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