Influence of Termination and Transfer on Molecular Weight Distribution of Polymers. I. Disproportionation and Combination
作者:
De-Yue Yan,
Gang-Feng Cai,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1986)
卷期:
Volume 23,
issue 1
页码: 37-57
ISSN:0022-233X
年代: 1986
DOI:10.1080/00222338608063374
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Expressions for the molecular size distribution, the average degree of polymerization, etc. are derived by means of the nonsteady-state method for addition polymerization with instantaneous initiation, termination by disproportionation, and combination. Furthermore, a theoretical method is established with which the curves of the differential molecular weight distribution and the values of other molecular parameters can be calculated from the initial conditions of polymerization and the monomer conversion or reaction time. This theory is suited to such types of polymerization as that of vinyl monomers radiated by60Co under deep-freezing conditions, the resultant not very reactive free radical accumulating, then stopping the radiation, and letting the polymerization begin at a higher temperature.
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