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Synthese und Komplexchemie funktionalisierter Tripod‐Liganden RC(CH2PPh2)3

 

作者: Bernd C. Janssen,   Volker Sernau,   Grottfried Huttner,   Alexander Asam,   Olaf Walter,   Michael Büchner,   Laszlo Zsolnai,  

 

期刊: Chemische Berichte  （WILEY Available online 1995）
卷期: Volume 128, issue 1  

页码: 63-70

 

ISSN:0009-2940

 

年代: 1995

 

DOI:10.1002/cber.19951280109

 

出版商: WILEY‐VCH Verlag

 

关键词: Tripod ligand synthesis;Tripod nickel chloro complexes;Tripod iron tris(acetonitrile) complexes;Tripod cobalt acetate complexes

 

数据来源: WILEY

 

摘要:

AbstractSynthesis and Complex Chemistry of Functionalised Tripod Ligands RC(CH2PPh2)3Malonic ester1is alkylated and converted into the triols RC(CH2OH)3(5). These are easily converted into the corresponding functionalised tripodal ligands RC(CH2PPh2)3(7) with R  Bzl (a),n‐C12H25(b), (CH3)2CH(CH2)2(c). Crystals suitable for X‐ray crystallography have been obtained of the ligand7a. In addition, the tripod ligands7aand7chave been further characterized by the syntheses and X‐ray analyses of the nickel complex [(7a)NiCl] (8a), the iron complex [(7c)Fe(NCCH3)3](BF4)2[9· (BF4)2], and the cobalt complex [(7c)Co{O(O)CCH3}](BPh4) (

 

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