Recent Advances in Pulse Cyclic and Square-Wave Cyclic Voltammetric Analysis
作者:
GordonN. Eccles,
期刊:
Critical Reviews in Analytical Chemistry
(Taylor Available online 1991)
卷期:
Volume 22,
issue 5
页码: 345-380
ISSN:1040-8347
年代: 1991
DOI:10.1080/10408349108051639
出版商: Taylor & Francis Group
关键词: square-wave;cyclic voltammetry;pulse cyclic voltammetry;square-wave cyclic voltammetry;linear sweep
数据来源: Taylor
摘要:
If rapid quantitative electrochemical analysis was to evolve, the charging current that plagues electrochemical measurements had to be minimized. These currents occur when rapidly changing potentials are applied to an electrode solution interface. This initated the research of modified potential waveforms such as those used in pulse and square wave polarography. These methods have been shown to filter out much of the effect of charging current and are used extensively in routine analysis. Similarly, pulse methods coupled with cyclic voltammetry also reduce noise and analysis times and in addition provide more qualitative information. A historical review of the various techniques that reject charging current is discussed with emphasis placed on recent studies with modified cyclic voltammetry waveforms.
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