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Three‐dimensional model studies of the effect of NOxemissions from aircraft on ozone in the upper troposphere over Europe and the North Atlantic

 

作者: Frode Flatøy,   Øystein Hov,  

 

期刊: Journal of Geophysical Research: Atmospheres  (WILEY Available online 1996)
卷期: Volume 101, issue D1  

页码: 1401-1422

 

ISSN:0148-0227

 

年代: 1996

 

DOI:10.1029/95JD03070

 

数据来源: WILEY

 

摘要:

A mesoscale chemistry transport model is coupled to a numerical weather prediction model (NWP) for Europe and the North Atlantic. It is applied to show that air traffic emissions significantly increase the concentrations of NOxas well as the net chemical formation rate of ozone over both the Atlantic Ocean and over central Europe. The time period studied was July 1–10, 1991, a period characterized by a high‐pressure ridge over North Europe. In convection the vertical gradient of NOxis strongly reduced because the midtropospheric concentrations increase. In the updraft region of convective plumes, chemical ozone formation up to 1.8 ppbv/h is calculated in the upper troposphere, and this is about a factor 50 higher than the average for 10.5 km over continental Europe during the 10‐day period. The high production rates are not sustained for more than a few hours, and it would be difficult to identify the effect of the process in a local measurement of the ozone concentration. The calculations indicate that 10–25 molecules of O3(0.03–0.05 ppb/h) are generated on the average per NOxmolecule emitted from aircraft (2–3 ppt/h). On convective days over regions with significant surface sources of NOx, ozone formation in the upper troposphere due to NOxbrought there by convection, outweighs the role of aircraft NOxemissions. The net chemical formation rate of ozone across the model domain depends on the boundary concentrations of NOxand O3, but the change in the upper troposphere in the net chemical formation rate of ozone induced by aircraft NOxemissions is quite independent of the concentrations

 

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