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Molecular weight of ethyl cellulose by dielectric dispersion of solutions in dioxane

 

作者: Philip C. Scherer,   M. C. Hawkins,   D. W. Levi,  

 

期刊: Journal of Polymer Science  (WILEY Available online 1958)
卷期: Volume 27, issue 115  

页码: 129-134

 

ISSN:0022-3832

 

年代: 1958

 

DOI:10.1002/pol.1958.1202711510

 

出版商: Interscience Publishers, Inc.

 

数据来源: WILEY

 

摘要:

AbstractThe dielectric dispersion of dilute solutions of ethyl cellulose in dioxane was studied using a “differential” bridge method for the range from 200 cycles to 300 kilocycles. The frequency where the dispersion was 0.50 was recorded as the “critical” frequency. The critical frequency is related to the intrinsic viscosity of the samples as log 100[η] = 2.97 − 0.59 (vc). Since the determination of critical frequency is very rapid this method apparently is satisfactory for molecular weight determinations in the syste

 

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