Crosslinked oligoethylene glycols: Correlation between their structure and some rheological properties
作者:
Dov Katz,
Gideon Salee,
期刊:
Journal of Polymer Science Part A‐2: Polymer Physics
(WILEY Available online 1968)
卷期:
Volume 6,
issue 5
页码: 801-811
ISSN:0449-2978
年代: 1968
DOI:10.1002/pol.1968.160060501
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractSix oligoethylene glycols were crosslinked with triphenylmethane triisocyanate, and polymers with systematically changing network chain lengths were obtained and investigated. The 10‐sec. torsion moduli versus temperature, glass transition temperatures, and cohesive energy densities of the polymers were determined and studied. The 10‐sec. torsion modulus versus temperature plots show that all six polymers have a glassy transition and rubbery region of rheological behavior. The front factor calculated from the equation for the torsion modulus in the rubbery region when measured values of the modulus were used was compared with the front factor computed from equations that take into consideration molecular structures of the rubbery networks. With the exception of the case of crosslinked diethylene glycol the agreement in all the other cases between the values obtained for the front factor in both ways was good. In the investigated range of temperatures the polymers have below the glass transition temperature another transition point. The solubility parameters of the polymers, calculated from swelling experiments, were with the exception of the first member in the series almost identi
点击下载:
PDF
(491KB)
返 回