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Preparation of Magnetic Amine Resins by Polymer Modification

 

作者: R.J. Eldridge,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1982)
卷期: Volume 17, issue 1  

页码: 167-173

 

ISSN:0022-233X

 

年代: 1982

 

DOI:10.1080/00222338208056474

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Weak acid ion exchangers prepared by graft polymerization of acrylic acid on cross-linked PVA microbeads containing magnetic iron oxide were converted to strong or weak base resins by reaction with glycidyltrimethylammonium chloride or with epichlorohydrin and diethylamine, respectively. Capacities up to 2.6 meq/g were obtained, but the products were susceptible to alkaline hydrolysis. Comparable resins prepared by grafting substituted methacrylic esters hydrolyzed more slowly, indicating that hydrolysis occurred at the ester linkage.

 

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