Preparation of Magnetic Amine Resins by Polymer Modification
作者:
R.J. Eldridge,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1982)
卷期:
Volume 17,
issue 1
页码: 167-173
ISSN:0022-233X
年代: 1982
DOI:10.1080/00222338208056474
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Weak acid ion exchangers prepared by graft polymerization of acrylic acid on cross-linked PVA microbeads containing magnetic iron oxide were converted to strong or weak base resins by reaction with glycidyltrimethylammonium chloride or with epichlorohydrin and diethylamine, respectively. Capacities up to 2.6 meq/g were obtained, but the products were susceptible to alkaline hydrolysis. Comparable resins prepared by grafting substituted methacrylic esters hydrolyzed more slowly, indicating that hydrolysis occurred at the ester linkage.
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